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Nickel-catalyzed reductive electrocarboxylation of disubstituted alkynes |
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| Affiliation: | 1. Key Laboratory of Green Chemistry & Technology of Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, China;2. State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, Zhejiang University of Technology, Hangzhou 310014, China;3. State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China |
| Abstract: | Electrochemically reduced Ni(bipy)3(BF4)2 catalyzes the reaction of carbon dioxide with disubstituted alkynes to yield mono- and di-carboxylated derivatives. The reaction is performed under mild conditions in an undivided cell fitted with a sacrificial magnesium anode. |
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