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Synthesis and characterization of new aromatic liquid crystalline polyesters having phenyl substituents
Authors:Tae-Gyu Choi  Sung-Jae Chung  Seung-Moo Huh  Yong-Kuk Yun  Jung-Il Jin
Abstract:Two different series of new aromatic liquid crystalline (LC) polyesters were prepared from 3-phenyl-4, 4'-biphenyldicarboxylic acid (PBDA) and 1-phenyl-2, 6-naphthalenedicarboxylic acid (PNDA). PBDA and PNDA were polymerized with various aromatic diols such as hydroquinone, substituted hydroquinones, isomeric naphthalenediols and 4, 4'-biphenol, and the resulting polyesters were characterized by DSC, WAXD, and on a cross-polarizing microscope for the study of their thermal transition and crystallization properties, and mesophases formed therefrom.
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