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Ion-solvent interaction in nonaqueous solutions. II. Spin-lattice relaxation times of23Na and133Cs
Authors:Yu M Kessler  A I Mishustin  A I Podkovyrin
Institution:(1) Moscow Institute of Chemical Engineering, Karl Marx Street 21/4, B-66 Moscow, USSR
Abstract:The spin-lattice relaxation time (T 1) of 23 Na was measured in solutions of NaClO 4 and (or) NaBr in formamide,N-methylformamide,N,N-dimethylformamide (DMF), MeCN, Me2CO, tetrahydrofuran (THF), and dimethyl sulfoxide (DMSO), and 133 Cs in a solution of CsCl in formamide. The values of (1/T 1) 0 obtained by extrapolation are discussed in terms of current theories of quadrupolar magnetic relaxation of ionic nuclei. A correlation was found between (1/T 1) 0 for 23 Na and Gutmann's donor numbers.For Part I, see ref. 1.
Keywords:23Na and133Cs NMR relaxation  ion-solvent interaction  N-methylformamide  N  N-dimethylformamide  CH3CN  acetone  tetrahydrofuran  dimethyl sulfoxide  CsCl  formamide  Gutmann numbers
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