Oxozirconium(IV) alkoxides |
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| Authors: | Ram Chand Paul Surinder Kumar Gupta Veena Goyal Sham Kumar Vasisht |
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| Affiliation: | (1) Department of Chemistry, Panjab University, 160014 Chandigarh, India |
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| Abstract: | Oxozirconium(IV) alkoxides of the type ZrO(OR)2·ROH and ZrOCl(OR)·2 ROH, where R is methyl, ethyl, and isopropyl, and ZrO(OCMe3)2·0.5Me3COH and ZrOCl(OCMe3)·1.5Me3COH have been prepared by the reaction of dichloroxozirconium(IV)-2-acetic acid with corresponding alcohols in the presence of appropriate amounts of piperidine. The alkoxides have been isolated and characterised through infrared, thermal and conductance studies. |
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