Synthesis and characterization of cyano complexes of oxotungsten(IV) with morpholinomethyl urea and related ligands |
| |
| Authors: | M S Pathania H N Sheikh B L Kalsotra |
| |
| Institution: | (1) Department of Chemistry, University of Jammu, Baba Sahib Ambedakar Road New Campus, Jammu, 180 006, India |
| |
| Abstract: | The synthesis and characterization of complexes, (Ph3P)2NH2WO(CN)3L-L] · 3H2O and CsWO(CN)3L-L] · H2O (where L-L = morpholinomethylurea, morpholinomethylthiourea, piperidinomethylurea, piperidinomethylthiourea, pyrrolidinomethylurea,
and pyrrolidinomethythiourea) are presented. The complexes have been prepared by the reaction of K3NaWO2(CN)4] · 6H2O with morpholinomethylurea and related ligands in aqueous solution around a pH of 7. These have been isolated as bis(triphenylphospine)imminium
or cesium salts. The complexes have been characterized by elemental analysis, ℝ, UV-Vis spectra, magnetic susceptibility and
conductivity measurements in addition to TGA/DTA
The text was submitted by the authors in English. |
| |
| Keywords: | Morpholinomethylurea morpholinomethylthiourea oxotungsten(IV) spin paired configuration uniunivalent electrolytes |
| 本文献已被 SpringerLink 等数据库收录！ |
|
