Self-assembly of Polyaniline: Mechanism Study |
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| Authors: | Shi-yan Song Li-jia Pan Yun Li Yi Shi Lin Pu Rong Zhang You-dou Zheng |
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| Abstract: | Anisotropic polyaniline (PAni) plates decorated with self-aligned nanofiber arrays were synthesized under the hydrothermal conditions. The formation mechanism of the self-assembled structures was investigated by studying the effect on PAni micro-structure with additive electrolyte in reaction system, and numerical simulation for dependence of systematic electrostatic energy on cross angles of self-assembled nanofiber arrays in grid textured PAni plates. It is proposed that the electrostatic interaction based on ionic doping charges plays an important role in the formation of the self-assembled PAni structures. |
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| Keywords: | Polyaniline Self-assembly Ionic charge |
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