Synthesis and reactivity of metal-containing monomers |
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| Authors: | E. I. Klabunovskii E. I. Karpeiskaya G. I. Dzhardimalieva N. D. Golubeva A. D. Pomogailo |
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| Affiliation: | (1) N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp, 117913 Moscow, Russian Federation;(2) Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432 Chernogolovka, Moscow Region, Russian Federation |
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| Abstract: | Optically active mixed alkoxy orthotitanates with general formula Ti(OR1)2(OR2)(OR3) (R1=Et, Bun; R2=CH2CH2OCOC(Me)=CH2; R3=menthyl, CH(Me)CH2Me, CH(Ph)CH(NHMe)Me, CH(C9H6N)(C9H14N)) were obtained for the first time by transesterification. The TiIV monomers synthesized were characterized by elemental analysis, ozonolysis, and1H and13C NMR and IR spectroscopy. Polymer products with optical activity were obtained by liquid phase radical copolymerization of TiIV-containing monomers. For Part 51, see Ref. 1. Deceased. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1739–1743, September, 1999. |
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| Keywords: | mixed alkoxy orthotitanates optically active monomers transesterification titanium-containing monomers metal-containing polymers |
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