Synthesis and Crystal Structure of 2,3-Bis(dinitrofluoromethyl)-1,4-dioxane |
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| Authors: | B S Fedorov N I Golovina S P Smirnov I Sh Abdrakhmanov A I Firkin L O Atovmyan |
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| Institution: | (1) Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka;(2) State Scientific-Research Institute Kristall, Dzerzhinsk, Russia |
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| Abstract: | For the first time the dinitromethyl group was modified to dinitrofluoromethyl group in the series of aliphatic polynitro compounds in the case of the reaction of 1,1,4,4-tetranitro-2,3-butanediol diacetate with ammonium fluoroxysulfate in the presence of sodium bicarbonate and ethylene glycol. Previously unknown 2,3-bis(dinitrofluoromethyl)-1,4-dioxane was synthesized. Its structure was determined by X-ray diffraction analysis. |
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| Keywords: | ammonium fluoroxysulfate 2 3-bis(dinitrofluoromethyl)-1 4-dioxane X-ray diffraction analysis fluorination |
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