Formation constants of some mercury(II) complexes determined from their anodic polarographic signals |
| |
Authors: | Esteban M Casassas E Fernandez L |
| |
Institution: | Departament de Química Analítica, Facultat de Química, Universitat de Barcelona, Av. Diagonal 647, 08028 Barcelona, Spain. |
| |
Abstract: | The formation constants of some Hg(II) complexes have been determined from the anodic polarographic signals for the oxidation of mercury in the presence of the following ligands: thiourea and its phenyl- and diphenyl-derivatives, thiocyanate, ethylenediamine, EDTA, methylthioacetic acid, 2,2'-thiobisacetic acid, 3,3'-thiobispropanoic acid, 2,2'-1,1-methandiylbis(thio)]bisacetic acid and 2,2'-1,2-ethandiylbis(thio)]bisacetic acid. The use of differential pulse polarography and a.c. polarography instead of d.c. polarography increases the accuracy and precision of the potential measurements and, as a consequence, of the stability constants determined. The results obtained by the different methods are compared. |
| |
Keywords: | |
本文献已被 ScienceDirect PubMed 等数据库收录! |
|