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Application of the Prigogine-Flory-Patterson theory part II. Mixtures of a bicyclic compound,benzene, cyclohexane,n-hexane with a 1-alkene and a 1-alkyne
Authors:T M Letcher  R C Baxter
Institution:(1) Department of Chemistry, Rhodes University, 6140 Grahamstown, South Africa
Abstract:The Prigogine-Flory-Patterson theory of liquid mixtures has been applied to the H m E and V m E for binary mixtures of an n-alkane with decalin, bicyclohexyl, tetralin, cyclohexylbenzene, benzene, cyclohexane and n-hexane with 1-hexene, 1-hexyne, 1-heptene and 1-heptyne. Furthermore the Prigogine-Flory theory has been used to predict activity coefficients at infinite dilution from the experimentally determined H m E at 25°C for the mixtures 1-hexene, 1-hexyne, 1-heptene, 1-heptyne with decalin, bicyclohexyl, tetralin and cyclohexylbenzene. The predictions are compared to experimental results.
Keywords:Excess molar enthalpies  excess molar volumes  decalin  bicyclohexyl  tetralin  cyclohexylbenzene  benzene  cyclohexane  1-hexene  1-hexyne  1-heptene  1-heptyne  Prigogine-Flory-Patterson theory  Prigogine-Flory theory  activity coefficients at infinite dilution
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