Synthesis of methylvinylpolyfluoroalkoxysilanes by photoinitiated radical reaction of dialkoxy(methyl)vinylsilanes with perfluoro-4-methylpent-2-ene |
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| Authors: | N. A. Chernyavskaya M. A. Kurykin |
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| Affiliation: | (1) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813 Moscow, Russian Federation |
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| Abstract: | A new method was elaborated for the synthesis of vinylsilanes with polyfluoroalkoxy substituents at the silicon atom using the photoinitiated radical reaction of dialkoxy(methyl)vinylsilanes with perfluoro-4-metliylpent-2-ene in the presence of di-tert-butyl peroxide at room temperature.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2976–2978, December, 1996, |
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| Keywords: | dialkoxy(methyl)vinylsilanes perfluoro-4-methylpent-2-ene radical addition |
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