Calculation of Fundamental Thermochemical Parameters of Phosphoranes by the Additivity Scheme |
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| Authors: | E. V. Sagadeev Yu. G. Safina R. A. Cherkasov |
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| Affiliation: | (1) Kazan State Technological University, ul. K. Marksa 68, Kazan, Tatarstan, 420015, Russia;(2) Kazan State University, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008, Russia |
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| Abstract: | Using the additivity scheme, experimental enthalpies of vaporization and formation of phosphoranes were analyzed, group contributions to the enthalpies of vaporization and formation were determined, and thermochemical parameters of five-coordinate phosphorus derivatives were calculated. |
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