Structure of Substituted 5-Chloromethyloxazolidines |
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| Authors: | O F Bulatova O B Chalova D L Rakhmankulov |
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| Institution: | (1) Research Institute of Small-scale Chemical Products and Reagents, Ufa, Bashkortostan, 450029, Russia;(2) Ufa State Petroleum Technical University, Ufa, Bashkortostan, 450029, Russia |
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| Abstract: | By means of 1H NMR spectroscopy isomerism was demonstrated in N-alkyl substituted 5-chloromethyl-1,3-oxazolidines due to relative cis-trans orientation of substituents in 2 and 5 positions of the ring. The preferred configuration in 2,3-diaryl-5-chloromethyl-1,3-oxazolidines, cis-(2R,5R), was proved by quantum-chemical calculations. |
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