| 反射薄层光谱电化学方法的应用 |
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| 引用本文： | 邹明珠 生桂华. 反射薄层光谱电化学方法的应用[J]. 高等学校化学学报, 1992, 13(6): 741-744 |
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| 作者姓名： | 邹明珠 生桂华 |
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| 作者单位： | 吉林大学化学系，吉林大学化学系，吉林大学化学系 长春，130023，长春，130023，长春，130023 |
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| 摘 要： | 用自行设计的反射光谱薄层电解池测定了二茂铁在NaClO_1/CH_3CN中的E~O′和n值、铁氰化钾在KCl底液中和亚甲蓝在KNO_3/DMSO中的扩散系数。对亚甲蓝在二甲亚砜介质中的还原过程进行了研究,证明有一电子还原产物存在。
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| 关 键 词： | 反射薄层池 光谱电化学 |
Application of Reflectance Thin-layer Spectroelectrochemical Method |
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| ZOU Ming-zhu,SHENG Gui-hua,ZHENG Yan-sheng. Application of Reflectance Thin-layer Spectroelectrochemical Method[J]. Chemical Research In Chinese Universities, 1992, 13(6): 741-744 |
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| Authors: | ZOU Ming-zhu SHENG Gui-hua ZHENG Yan-sheng |
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| Abstract: | With ferrocene and methylene blue in nonaqueous solvents, we tested the characteristic of the reflectance thin-layer spectroelectrochcmical cell which was designed by ourselves. We observed a very good response of optical signal to electrosignal. We determined the E0' and n values of ferrocene and the diffusion coefficients of potassium ferrocyanide and methylene blue. The mechanism of methylene blue being reduced in DMSO medium was investigated. |
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| Keywords: | Reflectance thin-layer cell Ferrocene Methylene blue Spectroelectrochemical method |
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