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Epoxidation reaction of perfluoroalkenes with tert-amine N-oxide |
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| Authors: | Xing Wei Caia b Min Shaa Biao Jiangc Ren Ming Pana a |
| Affiliation: | School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China ; School of Biological and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003,China ; Shanghai Institute of Organic Chemistry, Chinese Academy of Science, Shanghai 200032, China |
| Abstract: | Straight-chain aliphatic tert-amine N-oxides was found to be useful oxidizing agent for epoxidation of tri- and tetra-substituted perfluoroalkenes under mild conditions in high yields. The process for epoxidation by employing tri-n-butylamine N-oxide gave the best result in the reagent survey. |
| Keywords: | Epoxidation Catalytic tert-Amine N-oxides |
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