Synthesis of Sterically Hindered Secondary and Tertiary Alkyl(Aryl)Phosphines |
| |
| Authors: | Yu. A. Veits E. A. Neganova O. S. Vinogradova |
| |
| Affiliation: | (1) Lomonosov Moscow State University, Moscow, Russia |
| |
| Abstract: | Cross coupling of silylphosphines with 2-halobenzenecarboxylates or 2-halophenyl ethers, catalyzed with zero-valent palladium complexes can not be used as a procedure for preparing sterically hindered tertiary phosphines. The latter compounds can be successfully prepared by means of phosphorylation of corresponding o-lithiated derivatives.__________Translated from Zhurnal Obshchei Khimii, Vol. 75, No. 2, 2005, pp. 239–243.Original Russian Text Copyright © 2005 by Veits, Neganova, Vinogradova. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
