Cyclophosphazene-supported tetranuclear copper assembly containing 15 contiguous inorganic rings |
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| Authors: | Chandrasekhar Vadapalli Andavan Gurusamy Thangavelu Senthil Azhakar Ramachandran Pandian Balasubramanian Murugesa |
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| Institution: | Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur 208 016, India. vc@iitk.ac.in |
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| Abstract: | The cyclophosphazene hydrazide gem-N3P3Ph2N(Me)NH2]4 was reacted with o-hydroxybenzaldehyde to afford the multisite coordination ligand gem-N3P3Ph2N(Me)N=CHC6H4-2-OH]4 (LH4). The latter reacted with copper(II) salts to afford a novel tetranuclear copper assembly {N3P3Ph2N(Me)N=CHC6H4-2-O]4Cu2}2, which contains, remarkably, 15 contiguous inorganic rings. |
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