Photoelectrochemical reaction of chlorophyll immobilized with liquid crystal on metal surface |
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| Authors: | Masuo Aizawa Nobukazu Suzuki Fujio Takahashi Shuichi Suzuki |
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| Institution: | 1. Research Laboratory of Resources Utilization, Tokyo Institute of Technology, Nagatsuta, Midori-ku, 227, Yokohama, Japan
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| Abstract: | Chlorophyll was immobilized with liquid crystal on a platinum surface to prepare a photoexcitable electrode. Liquid crystals such as N-(p-methoxybenzylidene)-p-butylanil-ine were found to be effective on the photoexcitation of the immobilized chlorophyll. Such a chlorophyll-liquid crystal electrode produced photocurrent when it was coupled with a solution of nicotinamide adenine dinucleotide and exposed to light. The electron transfer accompanied by the photoelectrochemical reaction is discussed. |
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