Reusable amine-based structural motifs for green house gas (CO2) fixation |
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| Authors: | Dalapati Sasanka Jana Sankar Saha Rajat Alam Md Akhtarul Guchhait Nikhil |
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| Institution: | Department of Chemistry, University of Calcutta, 92 A. P. C. Road, Kolkata 700 009, India. |
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| Abstract: | A series of compounds with an amine based structural motif (ASM) have been synthesized for efficient atmospheric CO(2) fixation. The H-bonded ASM-bicarbonate complexes were formed with an in situ generated HCO(3)(-) ion. The complexes have been characterized by IR, (13)C NMR, and X-ray single-crystal structural analysis. ASM-bicarbonate salts have been converted to pure ASMs in quantitative yield under mild conditions for recycling processes. |
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