Molecular cable-like 1-D iodic spiral chains covered with triple helices stabilized in guest-included chiral porous framework |
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| Authors: | Tadokoro Makoto Tanaka Yasuko Noguchi Khoichiro Sugaya Tomoaki Isoda Kyosuke |
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| Affiliation: | Tokyo University of Science, Faculty of Science, Department of Chemistry, Kagurazaka 1-3, Tokyo 162-8601, Japan. tadokoro@rs.kagu.tus.ac.jp |
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| Abstract: | The supramolecular crystal {[Pr(DMFA)](3)[Ni(II)(Hbim)(3)](2)I}(n) with intricate chiral networks of [Ni(II)(Hbim)(3)](-) molecules is reported. It includes a cationic architecture as a guest, constructed from chiral nanotubes that penetrate I(-) chains with spiral channels wrapped by triple helices. The I(-) chains have AC conductivity in crystals like a molecular cable. |
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