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Two new triterpene glycosides from the holothurian Duasmodactyla kurilensis
Authors:S. A. Avilov  A. I. Kalinovskii  V. A. Stonik
Abstract:Two new glycosides have been isolated from the total triterpene glycosides of the holothurianDuasmodactyla kurilensis: kurilosides A (III) and C (IV). It has been established that (III) is 16agr-acetoxy-3beta-{[O-beta-D-glucopyranosyl-(1 rarr 4)-O-beta-D-quinovopyranosyl-(1 rarr 2)]-[O-(3-O-methyl-beta-D-glucopyranosyl)-(1 rarr 3)-O-(6-O-(sodium sulfato)-beta-D-glucopyranosyl)-(1 rarr 4)]-beta-D-xylopyranosyloxy}-4,4,14-trimethylpregen-9(11)-en-20-one, while the minor glycoside (IV) is 16agr-acetoxy-3beta-{O-beta-D-quinovopyranosyl-(1 rarr 2)-[O-(3-O-methyl-beta-D-glucopyranosyl-(1 rarr 3)-O-(6-O-(sodium sulfato)-beta-D-glucopyranosyl)-(1 rarr 4)]-beta-D-xylopyranosyloxy}-4,4,14-trimethylpregn-9(11)-en-20-one.Pacific Ocean Institute of Bioorganic Chemistry, Far Eastern Branch, Academy of Sciences of the USSR, Vladivostok. Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 221–226, March–April, 1991.
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