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Axially chiral directly beta,beta-linked bisporphyrins: synthesis and stereostructure
Authors:Bringmann Gerhard  Rüdenauer Stefan  Götz Daniel C G  Gulder Tobias A M  Reichert Matthias
Institution:Institute of Organic Chemistry, University of Würzburg, Am Hubland, D-97074 Würzburg, Germany. bringman@chemie.uni-wuerzburg.de
Abstract:reaction: see text] A novel type of "superbiaryl", the first porphyrin dimers with an intrinsically chiral structure, has been prepared. The atropo-enantiomers were configurationally assigned by HPLC-CD combined with quantum chemical CD calculations.
Keywords:
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