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可控纳米银胶体的稳定性
引用本文:李鑫,魏先福,杨力.可控纳米银胶体的稳定性[J].无机化学学报,2015,31(1):37-44.
作者姓名:李鑫  魏先福  杨力
作者单位:1. 北京印刷学院,印刷与包装工程学院,北京 102600
2. 北京印刷学院,印刷与包装工程学院,北京 102600;Innventia,Drottning Kristinas v(a)g 61,11486 Stockholm(斯德哥尔摩),Sweden(瑞典)
基金项目:国家自然科学基金面上项目(No.61474144)资助
摘    要:纳米银胶体(AgNPs)长期储存不稳定性问题是本研究的中心,着重考察了不同前驱体对纳米银胶体的稳定性影响。分别以银氨(Ag(NH3)2]OH)溶液和Ag NO3溶液为前驱体制备了多份纳米银胶体样品并通过UV-Vis、FE-SEM、EDS、ZETA电位仪等现代分析测试手段研究了纳米银胶的形貌、粒径大小以及稳定性。对比分析发现,以Ag(NH3)2]OH溶液为前驱体,制备的纳米银胶体具有粒径可控,尺寸均一,分散性良好等特点;而且经过一个月的常温储存,表现出比用Ag NO3溶液为前驱体制备的纳米银胶体具有更高的储存稳定性。

关 键 词:纳米银  银氨  胶体稳定性  晶体生长机理  导电墨水
收稿时间:6/4/2014 12:00:00 AM
修稿时间:2014/9/20 0:00:00

On the Long-Term Stability of Silver Nanoparticle Hydrocolloid
LI Xin,WEI Xian-Fu and YANG Li.On the Long-Term Stability of Silver Nanoparticle Hydrocolloid[J].Chinese Journal of Inorganic Chemistry,2015,31(1):37-44.
Authors:LI Xin  WEI Xian-Fu and YANG Li
Institution:Beijing Institute of Graphic Communication, School of Printing and Packaging, Beijing 102600, China;Beijing Institute of Graphic Communication, School of Printing and Packaging, Beijing 102600, China;Beijing Institute of Graphic Communication, School of Printing and Packaging, Beijing 102600, China;Innventia, Drottning Kristinas väg 61, 11486 Stockholm, Sweden
Abstract:This paper focuses on the long-term storage (in-shelf) stability issues of controllable silver nanoparticle hydrocolloids (AgNPs). Two controllable AgNPs were prepared from two different precursors: silver nitrate (AgNO3) and silver diamminohydroxide (Ag(NH3)2]OH). The important characteristics of the AgNPs were measured by means of UV-Vis, SEM, EDS, ZETA electric potential techniques as well as mathematical simulations. The comparative studies show that the AgNPs obtained from the Ag(NH3)2]OH precursor exhibited superior controlla-bility in particle size, size-distribution and dispensability in one month storage, compared to those obtained from AgNO3.
Keywords:silver nanoparticle (AgNPs)  silver ammonia  hydrocolloid stability  crystal growth mechanism  conductive ink
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