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12种嘌呤类化合物的滤纸基质室温燐光法研究
引用本文:尚晓红,董川,朱若华,晋卫军,魏雁声,刘长松. 12种嘌呤类化合物的滤纸基质室温燐光法研究[J]. 分析化学, 1998, 0(9)
作者姓名:尚晓红  董川  朱若华  晋卫军  魏雁声  刘长松
作者单位:山西医科大学公共卫生学院(尚晓红),山西大学化学系!太原030006(董川,朱若华,晋卫军,魏雁声,刘长松)
摘    要:较为详细地研究了12种嘌呤类化合物以滤纸为基质的室温燐光(RTP)光谱特性与分子结构的关系,以及重原子效应和酸度效应对RTP的影响。

关 键 词:滤纸基质  室温燐光  嘌呤类化合物

Solid Surface Room Temperature Phosphorescence of Twelve Purine Derivatives
Shang Xiaohong,Dong Chuan,Zhu Ruohua,Jin Weijun,Wei Yanshang,Liu Changsong. Solid Surface Room Temperature Phosphorescence of Twelve Purine Derivatives[J]. Chinese Journal of Analytical Chemistry, 1998, 0(9)
Authors:Shang Xiaohong  Dong Chuan  Zhu Ruohua  Jin Weijun  Wei Yanshang  Liu Changsong
Abstract:The solid surface room temperature phosphorescence (SS-RTP) of twelve purine derivatives using China-made filter paper as solid substrate was given. The relation between molecular structure and spetrum, the effects of heavy atoms and acidity on RTP were studied in detail. The experimental results showed that purine derivatives have analogous spectra. The maximal excitation wavelengths were round 280 nm, the maximal emission wavelengths were round 430 nm. For purine derivatives I- is a widely used heavy atom. The effect of pH on RTP intensity is related to the molecular structure.
Keywords:Room temperature phosphorescence   purine derivatives   solid substrate  
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