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Multivariate Statistical Assessment of Air Quality: A Case Study
Authors:Vasil Simeonov  Stefan Tsakovski  Tomaz Lavric  Pavlina Simeonova  Hans Puxbaum
Institution:(1) Chair of Analytical Chemistry, Faculty of Chemistry, University of Sofia ldquoSt. Kl. Okhridskirdquo, J. Bourchier Blvd. 1, 1164 Sofia, Bulgaria;(2) Institute of Chemical Technologies and Analytics, Vienna University of Technology, Getreidemarkt 9/164, 1060 Vienna, Austria;(3) Institute of Solid State Physics, Bulgarian Academy of Sciences, Tzarigradsko Chaussee 72, 1784 Sofia, Bulgaria
Abstract:The present paper deals with the application of several chemometrical methods (cluster and principal components analysis, source apportioning on absolute principal components scores) to an aerosol data collection from Unterloibach, Austria. It is shown that seven latent factors explaining almost 80% of the total variance are responsible for the data structure and are conditionally identified as ldquosecondary aerosolrdquo, ldquomineral dustrdquo, ldquooil burningrdquo, ldquolead smelterrdquo, ldquocoal burningrdquo, ldquosaltrdquo and ldquofertilizerrdquo emission sources. Furthermore, the contribution of each identified source to the formation of the particle total mass and chemical compounds total concentration is calculated. Thus, a reliable assessment of the air quality in the region is performed. The requirements of the sustainability concept for ecological indicators in this case is easily transformed into a multivariate statistical problem taking into account not separate indicators but the specific multivariate nature of aerosol pollution.
Keywords:: Chemometrics  air quality  cluster analysis  principal components analysis  source apportioning  
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