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Mechanism of Ozonolysis
Authors:Rudolf Criegee
Abstract:The formation of ozonides (1,2,4-trioxolanes) from alkenes and ozone can be described as a succession of three [2+3] cycloadditions or cycloreversions involving primary ozonides (1,2,3-trioxolanes) and aldehyde or ketone oxides as decisive intermediates, all of which have finite lifetimes. There is no warranted experimental basis for assuming an alternative mechanism.
Keywords:Ozonolysis  Reaction mechanisms
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