Nd3+螯合物的含氢有机溶液光谱性能研究

研究了Nd(TTA)₃螯合物溶于二甲基甲酰胺溶剂的光谱性质，溶液中所有氢未置换为氘.测量了这种溶液体系的吸收谱、荧光谱和荧光寿命.在898和1058 nm波长处观察到明显的Nd³⁺荧光特征峰.用Judd-Ofelt理论对吸收谱进行分析计算，得到了三个强度参数Ω_t(t=2,4,6)分别为Ω₂=4.9×10^-20 cm², Ω₄=5.1×10^-20 cm²和Ω₆=2.5×10^-20 cm².利用强度参数计算了⁴F_3/2能级与⁴I_9/2和⁴I_11/2之间的跃迁强度S_ed、自发辐射系数A_ed以及荧光分支比β等，估算了⁴F_3/2能级的辐射跃迁寿命τ_r＝682 μs.实测1058和898 nm波长处荧光寿命τ大约为460和505 μs，因此荧光量子效率分别高达0.67和0.74.荧光量子效率高表明Nd³⁺在这种溶液中无辐射跃迁比较弱；强度参数Ω₂比较大，表明Nd³⁺在溶液中具有不对称配位场环境，不对称的配位场环境可大大促进Nd³⁺吸收激发能量.光谱质量因子Ω₄/Ω₆>1，使得898 nm的辐射强于1058 nm的辐射.关键词：Nd有机溶液光谱性能Judd-Ofelt理论

Spectral properties of hydrogen-containing organic solution of neodymium chelate

Tris-thenoyltrifluroacetonate of Nd³⁺ has been prepared and dissolved in DMF solation with very high concentration, and the contained hydrogen has not been substituted by deuterium. The absorption spectrum, emission spectrum, and fluorescence lifetime of the solution were measured. Very obvious characteristic fluorescence peaks were observed at 898 and 1058 nm. Based on Judd-Ofelt theory, three intensity parameters were obtained: Ω₂=4.9×10^-20 cm², Ω₄=5.1×10^-20 cm² and Ω₆=2.5×10^-20 cm². Line strengths S_cal, oscillator strengths f_cal, radiative transition probabilities A_ed, radiative lifetimes τ_r and branch ratios β were calculated too. The measured lifetime τ of 1058 nm peak is 460 μs, and that of 898 nm 505 μs. Comparison between theoretically computed radiative lifetime τ_r (682 μs) and the measured lifetime indicates that the non-radiative transition probability of the solution is very low and the fluorescence quantum efficiency very high. High values of three intensity parameters prove the high asymmetric surroundings of Nd³⁺, which is important for Nd³⁺ to absorb the excitation energy. Spectropic quality factor Ω₄/Ω₆>1 makes radiation at 898 nm stronger than at 1058 nm.