| 一种新颖1D链状聚合物[Ni(acac)2(dadpm)]∞的合成与晶体结构 |
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| 引用本文： | 支兴蕾,张文华,张勇,徐颖,陈金香,任志刚,郎建平. 一种新颖1D链状聚合物[Ni(acac)2(dadpm)]∞的合成与晶体结构[J]. 无机化学学报, 2005, 21(3): 417-420 |
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| 作者姓名： | 支兴蕾 张文华 张勇 徐颖 陈金香 任志刚 郎建平 |
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| 作者单位： | 1. 江苏省有机合成重点实验室,苏州大学化学化工学院,苏州,215006
2. 江苏省有机合成重点实验室,苏州大学化学化工学院,苏州,215006;中国科学院福建物质结构研究所,结构化学国家重点实验室,福州,350002 |
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| 基金项目： | 江苏省自然科学研究基金资助项目(No.BK2004205)，中科院福建物质结构研究所结构化学国家重点实验室开放基金资助项目(No.030066)，江苏省有机合成重点实验室开放基金资助项目(No.JSK001) |
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| 摘 要： | The title compound [Ni(acac)2(dadpm)]∞ (acac=acetylacetonate, dadpm=4,4′-diaminodiphenylmethane) was synthesized from Ni(acac)2·2H2O with dadpm in DMF. The structure was characterized by elemental analysis, IR spectroscopy, thermal analysis and single-crystal X-ray diffraction. X-ray analysis revealed that the central Ni atom is at a center of symmetry, and is octahedrally coordinated by four O atoms from two acac anions and two N atoms from two dadpm ligands. Each dadpm ligand, which has a two-fold axis passing through its methylene C atom, bridges two Ni atoms to form a 1D polymeric chain. Neighboring chains connect via H bonding interactions to generate a 2D network. It crystallizes in the monoclinic system, space group P2/c with a=0.556 79(7), b=0.896 06(12), c=2.187 3(3) nm, β=94.942(3)°, V=1.087 2(3) nm3, Z=2, Dc=1.390 g·cm-3, F(000)=480, Mr=455.17, μ(Mo Kα)=0.924 mm-1, R(F)=0.036 0, wR(F2)=0.101 0, S=1.013. CCDC: 254565.
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| 关 键 词： | 晶体结构； (4，4′-二氨基)二苯基甲烷； 合成； 配位聚合物 |
| 文章编号： | 1001-4861(2005)03-0417-04 |
| 收稿时间： | 2004-10-18 |
| 修稿时间： | 2004-10-18 |
Synthesis and Crystal Structure of a Novel 1D Chain Coordination Polymer [Ni(acac)2(dadpm)]∞ |
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| ZHI Xing-Lei,ZHANG Weng-Hu,ZHANG Yong,XU Ying,CHEN Jin-Xiang,REN Zhi-Gang and LANG Jian-Ping. Synthesis and Crystal Structure of a Novel 1D Chain Coordination Polymer [Ni(acac)2(dadpm)]∞[J]. Chinese Journal of Inorganic Chemistry, 2005, 21(3): 417-420 |
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| Authors: | ZHI Xing-Lei ZHANG Weng-Hu ZHANG Yong XU Ying CHEN Jin-Xiang REN Zhi-Gang LANG Jian-Ping |
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| Affiliation: | Key Laboratory of Organic Synthesis of Jiangsu Province, School of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215006,Key Laboratory of Organic Synthesis of Jiangsu Province, School of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215006,Key Laboratory of Organic Synthesis of Jiangsu Province, School of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215006,Key Laboratory of Organic Synthesis of Jiangsu Province, School of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215006,Key Laboratory of Organic Synthesis of Jiangsu Province, School of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215006,Key Laboratory of Organic Synthesis of Jiangsu Province, School of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215006 and Key Laboratory of Organic Synthesis of Jiangsu Province, School of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215006;State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Acad |
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