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Binary nonadditive hard-sphere mixtures at high dimension |
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| Authors: | H -O Carmesin H L Frisch J K Percus |
| Institution: | (1) Courant Institute of Mathematical Sciences, New York University, 10012 New York, New York;(2) Chemistry Department, SUNY at Albany, 12222 New York, New York;(3) Universität Bremen, Postfach 330 440, 2800 Bremen 33, Germany;(4) Physics Department, New York University, 10003 New York, New York |
| Abstract: | At high spatial dimension, a suitably scaled classical system of interacting particles truncates at second virial terms. A binary mixture of nonadditive hard spheres with sufficiently repulsive interaction between unlike particles decomposes at sufficiently high density into two coexisting phases. The region around the critical density behaves classically. |
| Keywords: | Hard-sphere mixture high dimensionality phase separation regular binary mixture |
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