首页 | 本学科首页   官方微博 | 高级检索  
     检索      


Living/controlled copolymerization of acrylates with nonactivated alkenes
Authors:Shengsheng Liu  Ayusman Sen
Abstract:The living/controlled copolymerization of methyl acrylate with 1‐alkenes and norbornene derivatives through several radical polymerization techniques has been achieved. These techniques include atom transfer radical polymerization, reversible addition–fragmentation transfer polymerization, nitroxide‐mediated polymerization, and degenerative transfer polymerization. These systems display many of the characteristics of a living polymerization process: the molecular weight increases linearly with the overall conversion, but the polydispersity remains low. Novel block copolymers have been synthesized through the sequential addition of monomers or chain extension. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 6175–6192, 2004
Keywords:radical polymerization  living polymerization  copolymerization  macromonomers  block copolymers
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号