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Direct measurement of structural diversity in single molecules of a chiral helical π‐conjugated polymer
Authors:Ken‐ichi Shinohara  Takeshi Kitami  Kouichi Nakamae
Abstract:Using a noncontact atomic force microscope, we found that single molecules in a chiral helical π‐conjugated polymer could form a unique periodic structure having a pitch of about 20 nm on the surface of a mica substrate. The diversity of the periodic structures is also discussed. Some basic insights into the characteristics of single molecules (or their individual characteristics) in π‐conjugated polymers are revealed. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 3930–3935, 2004
Keywords:single molecule  chiral helix  phenylacetylene polymer  direct observation  atomic force microscope (AFM)  structural diversity
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