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高岭土表面偶联改性及其对UPR性能的影响
引用本文:张一甫,曾竟成.高岭土表面偶联改性及其对UPR性能的影响[J].湖南理工学院学报,2002,15(4):55-57.
作者姓名:张一甫  曾竟成
作者单位:岳阳师范学院化学化工系 湖南岳阳414000 (张一甫),国防科技大学航天与材料工程学院 湖南长沙410073(曾竟成)
摘    要:介绍了用A - 15 1与钛酸酯偶联剂处理高岭土的方法 ,研究了处理剂的用量与偶联高岭土的加入量对UPR(不饱和聚酯树脂 )的拉伸强度和模量、弯曲强度和模量以及冲击强度的影响。试验结果表明 :经A - 15 1与钛酸酯处理的高岭土填充UPR的拉伸强度、弯曲强度以及冲击强度都有不同程度的提高。在A - 15 1处理浓度为 1% ,钛酸酯用量为 0 .8% ,偶联高岭土的填充量为 30 %时 ,UPR的拉伸强度、弯曲强度及冲击强度分别由4 4 .38MPa ,  72 .6 6MPa ,  9.6 8kJ/m2 提高到 5 6 .34MPa ,  98.31MPa ,  13.2 5kJ/m2 与 4 9.96MPa ,  89.6 5MPa ,  14 .5 6kJ/m2 ,增强效果明显。

关 键 词:高岭土  偶联  改性  不饱和聚酯树脂
文章编号:1008-620X(2002)04-0055-03
修稿时间:2002年9月16日

Couple Modification of Kaolin Surface and Effect on Performance of Unsaturated Polyester Resins
ZHANG Yi fu,ZEN Jing cheng.Couple Modification of Kaolin Surface and Effect on Performance of Unsaturated Polyester Resins[J].Journal of Hunan Institute of Science and Technology,2002,15(4):55-57.
Authors:ZHANG Yi fu  ZEN Jing cheng
Institution:ZHANG Yi fu 1 ZEN Jing cheng 2
Abstract:The process method of kaolin was introduced using A-151 and ester titanate coupling agent. Effect of dosage of A-151 and ester titanate coupling agent on stretch strength and modulus, bending strength and modulus , impact strength of UPR was investigated. Experiment showed that stretch strength, bending strength and impact strength of UPR were increased which was filled by treated kaolin. At A-151 1%, ester titanate 0.8,filled amount of coupling kaolin 30%, stretch strength, bending modulus and impact strength of UPR were increased from 44.38 MPa,72.66 MPa,9.68 KJ/m 2 to 56.34 MPa,98.31 MPa,13.25 kJ/m 2 and 49.96 MPa,89.65 MPa,14.56 kJ/m 2.Coupling kaolin had obvious effectiveness for filling UPR.
Keywords:kaolin  couple  modification  UPR
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