Poly(vinylpyridine) complexes of palladium as hydrogenation catalysts. Effect of polymeric ligand structure |
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| Authors: | D V Sokolskii A K Zharmagambetova S G Mukhamedzhanova E A Bekturov and S E Kudaibergenov |
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| Institution: | (1) Institute of Organic Catalysis and Electrochemistry, 480100 Alma-Ata, USSR |
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| Abstract: | The title complexes exhibit high catalytic activity, selectivity and stability in hydrogenation of allyl alcohol. The structure of a polymeric ligand (i.e. the position of the nitrogen atom in the pyridine ring) affects catalyst activity. According to the hydrogenation rates of allyl alcohol, the complexes studied are arranged in the sequence: P4VP-Pd>P2VP-Pd>P2M5VP-Pd.
                ,   -      - .  ( ) .    : 4 - >2-Pd>2 5-.
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