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Zur Kenntnis der Chemie der Silazane. IV. Über ein Sulfurylphosphazo-silazan |
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| Authors: | Udo Bieller Margot Becke-Goehring |
| Abstract: | Trichlorophosphazo-sulphurylchloride. Cl3P?N? SO2Cl, reacts with heptamethyldisilazane to yield the Si? N? P compound (I) formulated in ?Inhaltsübersicht”?. (I) reacts with PCl5 or C6H5? PCl4 forming the known 2,2,2,4,4,4-hexachloro-1,3-di-methylcyclo-diphosphazane(II), accompanied by the compound Cl3P?N? SO2Cl and C6H5? PCl2?N? SO2Cl, respectively, which were detected by means of 31P-NMR spectroscopy. |
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