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A mass-spectral study of exo- and endo-2-norbornyl bromide and exo and endo-8-bromobicyclo[3.2.1]octane by photoionization |
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| Authors: | D C DeJongh S R Shrader R G Isakson N A LeBel J H Beynon |
| Abstract: | The photoionization, as well as the electron-impact, mass spectra of exo-and endo-norbornyl bromide and of exo-and endo-8-bromobicyclo3.2.1]octane show that exo-Br loss is more facile than endo-Br loss in formation of C7H11⊕ and C8H13⊕, respectively. The relative intensity values are compared with solvolysis data from the same systems. |
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