Some physical properties of ZnS crystals grown from the vapour phase

Wurtzite-type crystals with wide regions of high purity and good optical properties have been grown in a few hours by an improved flow method. Dislocations have been found to be mainly arranged inside isolated striation regions where a weak green fluorescence and phosphorescence has been observed. Under bending deformation the crystals show a plastic behaviour that is not directly correlated to the mean dislocation density of the samples. Rupture has been found at about 10³ kg/cm².The microwave method for the detection of crystal deflection has been suggested by Prof. A. Gozzini. His helpful advice and interest in this research has been deeply appreciated. Many thanks are also due to the Physical Institute of SAV in Prague, for the possibility to work on their crystals of ZnS. Finally we wish to thank Mr. Coli and Mr. Montanari for design and construction of the mechanical equipment and the furnace quartz assembly.