On the mechanism of arylation of ethylene by palladium(II) |
| |
Authors: | I V Kozhevnikov and K I Matveev |
| |
Institution: | (1) Institute of Catalysis, Novosibirsk, USSR |
| |
Abstract: | The phenylation of ethylene with benzene under the effect of palladium acetate at C2H4] Pd(OAc)2] has been found to give styrene and trans-stilbene via parallel rather than consecutive reactions. The data obtained indicate that styrene and stilbene are formed through the same intermediate. The reaction mechanism is discussed.
![Ucy](/content/g652587u71468560/xxlarge1059.gif) ![scy](/content/g652587u71468560/xxlarge1089.gif) ![tcy](/content/g652587u71468560/xxlarge1090.gif) ![acy](/content/g652587u71468560/xxlarge1072.gif) ![ncy](/content/g652587u71468560/xxlarge1085.gif) ![ocy](/content/g652587u71468560/xxlarge1086.gif) ![vcy](/content/g652587u71468560/xxlarge1074.gif) ![lcy](/content/g652587u71468560/xxlarge1083.gif) ![iecy](/content/g652587u71468560/xxlarge1077.gif) ![ncy](/content/g652587u71468560/xxlarge1085.gif) , ![chcy](/content/g652587u71468560/xxlarge1095.gif) ![tcy](/content/g652587u71468560/xxlarge1090.gif) ![pcy](/content/g652587u71468560/xxlarge1087.gif) ![rcy](/content/g652587u71468560/xxlarge1088.gif) ![fcy](/content/g652587u71468560/xxlarge1092.gif) ![iecy](/content/g652587u71468560/xxlarge1077.gif) ![ncy](/content/g652587u71468560/xxlarge1085.gif) ![icy](/content/g652587u71468560/xxlarge1080.gif) ![lcy](/content/g652587u71468560/xxlarge1083.gif) ![icy](/content/g652587u71468560/xxlarge1080.gif) ![rcy](/content/g652587u71468560/xxlarge1088.gif) ![ocy](/content/g652587u71468560/xxlarge1086.gif) ![vcy](/content/g652587u71468560/xxlarge1074.gif) ![acy](/content/g652587u71468560/xxlarge1072.gif) ![ncy](/content/g652587u71468560/xxlarge1085.gif) ![icy](/content/g652587u71468560/xxlarge1080.gif) ![ecy](/content/g652587u71468560/xxlarge1101.gif) ![tcy](/content/g652587u71468560/xxlarge1090.gif) ![icy](/content/g652587u71468560/xxlarge1080.gif) ![lcy](/content/g652587u71468560/xxlarge1083.gif) ![iecy](/content/g652587u71468560/xxlarge1077.gif) ![ncy](/content/g652587u71468560/xxlarge1085.gif) ![bcy](/content/g652587u71468560/xxlarge1073.gif) ![iecy](/content/g652587u71468560/xxlarge1077.gif) ![ncy](/content/g652587u71468560/xxlarge1085.gif) ![zcy](/content/g652587u71468560/xxlarge1079.gif) ![ocy](/content/g652587u71468560/xxlarge1086.gif) ![lcy](/content/g652587u71468560/xxlarge1083.gif) ![ocy](/content/g652587u71468560/xxlarge1086.gif) ![pcy](/content/g652587u71468560/xxlarge1087.gif) ![ocy](/content/g652587u71468560/xxlarge1086.gif) ![dcy](/content/g652587u71468560/xxlarge1076.gif) ![iecy](/content/g652587u71468560/xxlarge1077.gif) ![jcy](/content/g652587u71468560/xxlarge1081.gif) ![scy](/content/g652587u71468560/xxlarge1089.gif) ![tcy](/content/g652587u71468560/xxlarge1090.gif) ![vcy](/content/g652587u71468560/xxlarge1074.gif) ![icy](/content/g652587u71468560/xxlarge1080.gif) ![iecy](/content/g652587u71468560/xxlarge1077.gif) ![acy](/content/g652587u71468560/xxlarge1072.gif) ![tscy](/content/g652587u71468560/xxlarge1094.gif) ![iecy](/content/g652587u71468560/xxlarge1077.gif) ![tcy](/content/g652587u71468560/xxlarge1090.gif) ![acy](/content/g652587u71468560/xxlarge1072.gif) ![tcy](/content/g652587u71468560/xxlarge1090.gif) ![pcy](/content/g652587u71468560/xxlarge1087.gif) ![acy](/content/g652587u71468560/xxlarge1072.gif) ![lcy](/content/g652587u71468560/xxlarge1083.gif) ![lcy](/content/g652587u71468560/xxlarge1083.gif) ![acy](/content/g652587u71468560/xxlarge1072.gif) ![dcy](/content/g652587u71468560/xxlarge1076.gif) ![icy](/content/g652587u71468560/xxlarge1080.gif) ![pcy](/content/g652587u71468560/xxlarge1087.gif) ![rcy](/content/g652587u71468560/xxlarge1088.gif) C2H4] Pd(OAc)2] ![scy](/content/g652587u71468560/xxlarge1089.gif) ![tcy](/content/g652587u71468560/xxlarge1090.gif) ![icy](/content/g652587u71468560/xxlarge1080.gif) ![rcy](/content/g652587u71468560/xxlarge1088.gif) ![ocy](/content/g652587u71468560/xxlarge1086.gif) ![tcy](/content/g652587u71468560/xxlarge1090.gif) ![rcy](/content/g652587u71468560/xxlarge1088.gif) ![acy](/content/g652587u71468560/xxlarge1072.gif) ![ncy](/content/g652587u71468560/xxlarge1085.gif) -![scy](/content/g652587u71468560/xxlarge1089.gif) ![tcy](/content/g652587u71468560/xxlarge1090.gif) ![icy](/content/g652587u71468560/xxlarge1080.gif) ![lcy](/content/g652587u71468560/xxlarge1083.gif) ![softcy](/content/g652587u71468560/xxlarge1100.gif) ![bcy](/content/g652587u71468560/xxlarge1073.gif) ![iecy](/content/g652587u71468560/xxlarge1077.gif) ![ocy](/content/g652587u71468560/xxlarge1086.gif) ![bcy](/content/g652587u71468560/xxlarge1073.gif) ![rcy](/content/g652587u71468560/xxlarge1088.gif) ![acy](/content/g652587u71468560/xxlarge1072.gif) ![zcy](/content/g652587u71468560/xxlarge1079.gif) ![ucy](/content/g652587u71468560/xxlarge1091.gif) ![yucy](/content/g652587u71468560/xxlarge1102.gif) ![tcy](/content/g652587u71468560/xxlarge1090.gif) ![scy](/content/g652587u71468560/xxlarge1089.gif) ![pcy](/content/g652587u71468560/xxlarge1087.gif) ![acy](/content/g652587u71468560/xxlarge1072.gif) ![rcy](/content/g652587u71468560/xxlarge1088.gif) ![acy](/content/g652587u71468560/xxlarge1072.gif) ![lcy](/content/g652587u71468560/xxlarge1083.gif) ![lcy](/content/g652587u71468560/xxlarge1083.gif) ![iecy](/content/g652587u71468560/xxlarge1077.gif) ![softcy](/content/g652587u71468560/xxlarge1100.gif) ![ncy](/content/g652587u71468560/xxlarge1085.gif) ![ycy](/content/g652587u71468560/xxlarge1099.gif) ![rcy](/content/g652587u71468560/xxlarge1088.gif) ![iecy](/content/g652587u71468560/xxlarge1077.gif) ![acy](/content/g652587u71468560/xxlarge1072.gif) ![kcy](/content/g652587u71468560/xxlarge1082.gif) ![tscy](/content/g652587u71468560/xxlarge1094.gif) ![icy](/content/g652587u71468560/xxlarge1080.gif) ![yacy](/content/g652587u71468560/xxlarge1103.gif) . ![Pcy](/content/g652587u71468560/xxlarge1055.gif) ![ocy](/content/g652587u71468560/xxlarge1086.gif) ![lcy](/content/g652587u71468560/xxlarge1083.gif) ![ucy](/content/g652587u71468560/xxlarge1091.gif) ![chcy](/content/g652587u71468560/xxlarge1095.gif) ![iecy](/content/g652587u71468560/xxlarge1077.gif) ![ncy](/content/g652587u71468560/xxlarge1085.gif) ![ncy](/content/g652587u71468560/xxlarge1085.gif) ![ycy](/content/g652587u71468560/xxlarge1099.gif) ![dcy](/content/g652587u71468560/xxlarge1076.gif) ![acy](/content/g652587u71468560/xxlarge1072.gif) ![ncy](/content/g652587u71468560/xxlarge1085.gif) ![ncy](/content/g652587u71468560/xxlarge1085.gif) ![ycy](/content/g652587u71468560/xxlarge1099.gif) ![pcy](/content/g652587u71468560/xxlarge1087.gif) ![ocy](/content/g652587u71468560/xxlarge1086.gif) ![zcy](/content/g652587u71468560/xxlarge1079.gif) ![vcy](/content/g652587u71468560/xxlarge1074.gif) ![ocy](/content/g652587u71468560/xxlarge1086.gif) ![lcy](/content/g652587u71468560/xxlarge1083.gif) ![yacy](/content/g652587u71468560/xxlarge1103.gif) ![yucy](/content/g652587u71468560/xxlarge1102.gif) ![pcy](/content/g652587u71468560/xxlarge1087.gif) ![ocy](/content/g652587u71468560/xxlarge1086.gif) ![lcy](/content/g652587u71468560/xxlarge1083.gif) ![acy](/content/g652587u71468560/xxlarge1072.gif) ![gcy](/content/g652587u71468560/xxlarge1075.gif) ![acy](/content/g652587u71468560/xxlarge1072.gif) ![tcy](/content/g652587u71468560/xxlarge1090.gif) , ![chcy](/content/g652587u71468560/xxlarge1095.gif) ![tcy](/content/g652587u71468560/xxlarge1090.gif) ![scy](/content/g652587u71468560/xxlarge1089.gif) ![tcy](/content/g652587u71468560/xxlarge1090.gif) ![icy](/content/g652587u71468560/xxlarge1080.gif) ![rcy](/content/g652587u71468560/xxlarge1088.gif) ![ocy](/content/g652587u71468560/xxlarge1086.gif) ![scy](/content/g652587u71468560/xxlarge1089.gif) ![tcy](/content/g652587u71468560/xxlarge1090.gif) ![icy](/content/g652587u71468560/xxlarge1080.gif) ![lcy](/content/g652587u71468560/xxlarge1083.gif) ![softcy](/content/g652587u71468560/xxlarge1100.gif) ![bcy](/content/g652587u71468560/xxlarge1073.gif) ![iecy](/content/g652587u71468560/xxlarge1077.gif) ![pcy](/content/g652587u71468560/xxlarge1087.gif) ![ocy](/content/g652587u71468560/xxlarge1086.gif) ![lcy](/content/g652587u71468560/xxlarge1083.gif) ![ucy](/content/g652587u71468560/xxlarge1091.gif) ![chcy](/content/g652587u71468560/xxlarge1095.gif) ![acy](/content/g652587u71468560/xxlarge1072.gif) ![yucy](/content/g652587u71468560/xxlarge1102.gif) ![tcy](/content/g652587u71468560/xxlarge1090.gif) ![scy](/content/g652587u71468560/xxlarge1089.gif) ![chcy](/content/g652587u71468560/xxlarge1095.gif) ![iecy](/content/g652587u71468560/xxlarge1077.gif) ![rcy](/content/g652587u71468560/xxlarge1088.gif) ![iecy](/content/g652587u71468560/xxlarge1077.gif) ![ocy](/content/g652587u71468560/xxlarge1086.gif) ![dcy](/content/g652587u71468560/xxlarge1076.gif) ![icy](/content/g652587u71468560/xxlarge1080.gif) ![icy](/content/g652587u71468560/xxlarge1080.gif) ![ncy](/content/g652587u71468560/xxlarge1085.gif) ![tcy](/content/g652587u71468560/xxlarge1090.gif) ![iecy](/content/g652587u71468560/xxlarge1077.gif) ![rcy](/content/g652587u71468560/xxlarge1088.gif) ![mcy](/content/g652587u71468560/xxlarge1084.gif) ![iecy](/content/g652587u71468560/xxlarge1077.gif) ![dcy](/content/g652587u71468560/xxlarge1076.gif) ![acy](/content/g652587u71468560/xxlarge1072.gif) . ![Ocy](/content/g652587u71468560/xxlarge1054.gif) ![bcy](/content/g652587u71468560/xxlarge1073.gif) ![scy](/content/g652587u71468560/xxlarge1089.gif) ![ucy](/content/g652587u71468560/xxlarge1091.gif) ![zhcy](/content/g652587u71468560/xxlarge1078.gif) ![dcy](/content/g652587u71468560/xxlarge1076.gif) ![acy](/content/g652587u71468560/xxlarge1072.gif) ![iecy](/content/g652587u71468560/xxlarge1077.gif) ![tcy](/content/g652587u71468560/xxlarge1090.gif) ![scy](/content/g652587u71468560/xxlarge1089.gif) ![mcy](/content/g652587u71468560/xxlarge1084.gif) ![iecy](/content/g652587u71468560/xxlarge1077.gif) ![khcy](/content/g652587u71468560/xxlarge1093.gif) ![acy](/content/g652587u71468560/xxlarge1072.gif) ![ncy](/content/g652587u71468560/xxlarge1085.gif) ![icy](/content/g652587u71468560/xxlarge1080.gif) ![zcy](/content/g652587u71468560/xxlarge1079.gif) ![rcy](/content/g652587u71468560/xxlarge1088.gif) ![iecy](/content/g652587u71468560/xxlarge1077.gif) ![acy](/content/g652587u71468560/xxlarge1072.gif) ![kcy](/content/g652587u71468560/xxlarge1082.gif) ![tscy](/content/g652587u71468560/xxlarge1094.gif) ![icy](/content/g652587u71468560/xxlarge1080.gif) .
|
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |