Violurato complexes of nickel(II). Formation equilibria. Deprotonation equilibria of the coordinated ligands and related stereochemical changes |
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Authors: | Enrique García-España José M Moratal J Faus |
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Institution: | (1) Departamento de Química Inorga ica, Facultad de Química de la Universidad de Valencia, Spain |
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Abstract: | Summary The formation equilibria of nickel(II) violurato-complexes in water and dimethylsulphoxide-water (80 20) as well as deprotonation of the coordinated ligands and related stereochemical changes are reported. The stability constants of the Ni2+-H2V– complexes log 1=5.06, Iog 2=9.38, log 3=12.98 as well as the acidity constants of the Ni(H2V)3]– complex, log j1= 8.37, log j2=15.76, log j3=22.37 are determined at 25 °C and 0.1M NaClO4. A new violurato-complex of Ni2+, Na4Ni(HV)3]5H2O, is isolated and characterized. |
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