CuPd Nanoparticles as a Robust Catalyst for Electrochemical Allylic Alkylation |
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Authors: | Zhouyang Yin Huan Pang Xuefeng Guo Honghong Lin Michelle Muzzio Mengqi Shen Kecheng Wei Chao Yu Paul Williard Shouheng Sun |
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Abstract: | An efficient CuPd nanoparticle (NP) catalyst (3 nm CuPd NPs deposited on carbon support) is designed for catalyzing electrochemical allylic alkylation in water/isopropanol (1:1 v/v) and 0.2 m KHCO3 solution at room temperature. The Pd catalysis was Pd/Cu composition‐dependent, and CuPd NPs with a Pd/Cu ratio close to one are the most efficient catalyst for the selective cross‐coupling of alkyl halides and allylic halides to form C?C hydrocarbons with product yields reaching up to 99 %. This NP‐catalyzed electrochemical allylic alkylation expands the synthetic scope of cross‐coupling reactions and can be further extended to other organic reaction systems for developing green chemistry electrosynthesis methods. |
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Keywords: | allylic alkylation CuPd nanoparticles electrocatalysis organic electrosynthesis |
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