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Faceted Branched Nickel Nanoparticles with Tunable Branch Length for High‐Activity Electrocatalytic Oxidation of Biomass
Authors:Agus R Poerwoprajitno  Lucy Gloag  John Watt  Steffen Cychy  Soshan Cheong  Priyank V Kumar  Tania M Benedetti  Chen Deng  Kuang‐Hsu Wu  Christopher E Marjo  Dale L Huber  Martin Muhler  J Justin Gooding  Wolfgang Schuhmann  Da‐Wei Wang  Richard D Tilley
Abstract:Controlling the formation of nanosized branched nanoparticles with high uniformity is one of the major challenges in synthesizing nanocatalysts with improved activity and stability. Using a cubic‐core hexagonal‐branch mechanism to form highly monodisperse branched nanoparticles, we vary the length of the nickel branches. Lengthening the nickel branches, with their high coverage of active facets, is shown to improve activity for electrocatalytic oxidation of 5‐hydroxymethylfurfural (HMF), as an example for biomass conversion.
Keywords:branched nickel  branching mechanisms  electrocatalysis  HMF oxidation  nanoparticle synthesis
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