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Enantioselective S−H Insertion Reactions of α‐Carbonyl Sulfoxonium Ylides |
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| Authors: | Patrícia B Momo Alexandria N Leveille Elliot H E Farrar Matthew N Grayson Anita E Mattson Antonio C B Burtoloso |
| Abstract: | The first example of enantioselective S?H insertion reactions of sulfoxonium ylides is reported. Under the influence of thiourea catalysis, excellent levels of enantiocontrol (up to 95 % ee) and yields (up to 97 %) are achieved for 31 examples in S?H insertion reactions of aryl thiols and α‐carbonyl sulfoxonium ylides. |
| Keywords: | aryl thiol enantioselectivity organocatalysis S− H insertion sulfoxonium ylide |