Interaction ofZ-1,2-borylphosphinoalkene with ketenimine |
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| Authors: | A S Balueva E R Mustakimov G N Nikonov Yu T Struchkov A P Pisarevsky R R Musin |
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| Institution: | (1) A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' Scientific Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420083 Kazan, Russian Federation;(2) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813 Moscow, Russian Federation |
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| Abstract: | N-Phenyl-C,C-diphenylketenimine adds toZ-1-butyl-I-dibutylboryl-2-diphenylphosphino-2-phenylethene to give 2,2,3-tributyl-6-diphenylmethylideno-1,4,5,5-tetraphenyl-1-aza-5-phosphonia-2-borataeyclohex-3-ene, which rearranges into 4,6-dibutyl-2-diphenylphosphino-1,1,3,5-tetraplienyl-3-aza-4-boradeca-1,5-diene upon heating. Its crystal structure has been established by X-ray analysis.Deceased in 1995.Translated from IIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. l, pp. 183–187, January, 1996. |
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| Keywords: | Z-1 2-borylphosphitloalkene N-phenyl-C C-diphenylketenimine 4 6-dibutyl-2-diphhenylphosphino-1 1 3 5-tetraphenyl-3-aza-4-boradeca-l 5-diene X-ray analysis |
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