Structure and properties of 1-(2-pyridyl)-3-phenyl-5-arylformazans |
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Authors: | L M Shegal L P Sidorova N P Bednyagina I L Shegal |
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Institution: | (1) N. P. Ogarev Mordovskii State University, Saransk;(2) S. M. Kirov Ural Polytechnic Institute, Sverdlovsk |
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Abstract: | A series of 1-(2-pyridyl)-3-phenyl-5-arylformazans, which form deeply colored complexes with Zn2+, Cu2+, Co2+, and Ni2+ salts, were obtained by coupling of arenediazonium salts, containing various substituants in the phenyl ring, with benzaldehyde 2-pyridylhydrazone. The presence of a nitro group causes deepening of the color and leads to the appearance of negative solvatochromism.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1379–1381, October, 1972. |
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