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Acid-catalyzed reactions of 3-(α-hydroxybenzyl)pyrazolo[1,5-a]pyridines
Authors:Yasuyoshi Miki  Osamu Tomii  Hayami Nakao  Mayumi Kubo  Hiroko Hachiken  Shoji Takemura  Masazumi Ikeda
Abstract:Treatment of 3-(or-hydroxybenzyl)pyrazolo1,5-a]pyridines with trifluoroacetic acid in dichloromethane resulted in the formation of pyrazolo1,5-a]pyridines, bisα-(pyrazolo1,5-a]pyrid-3-yl)benzyl] ethers, and phenylbis(pyrazolo1,5-a]pyrid-3-yl)methanes, depending upon the presence or absence of the substituents at the 2- and/or 4-positions and the reaction conditions employed.
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