Intramolecular Dynamics of Tetranuclear Iridium Carbonyl Cluster Compounds. Part 1. Bromotri-μ-carbonyloctacarbonyltetrairidate(1–) |
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Authors: | Andrs Strawczynski Renzo Ros Raymond Roulet |
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Institution: | Andrés Strawczynski,Renzo Ros,Raymond Roulet |
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Abstract: | A 2D and variable-temperature 13C-NMR study indicates that a CO-site exchange occurs in the title complex via several consecutive processes, the first being a ‘merry-go-round’ of the basal CO's, the second a switch of basal face not involving unbridged intermediates. |
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