Transition-Metal Complexes with Bidentate Ligands Spanning trans-Positions. Part XVII. Some platinum(II) complexes with anionic ligands such as methoxide,formate, carboxylate,hydride, and borohydride,and the X-ray crystal structure of [PtHCl(
)] (PP = 2,11-bis(diphenylphosphinomethyl)benzo[c]phenanthrene) |
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| Authors: | Gustav Bracher Bruno Kellenberger Luigi M Venanzi Fiorella Bachechi Luigi Zambonelli |
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| Abstract: | The complexes trans-PtXY( 2 ] (X = H or Me; Y = OMe, OCHO, CO2H, and BH4; 2 = 2,11-bis{bis3-(trifluoromethyl)phenyl]phosphinomethyl}benzoc]phenanthrene) were prepared, and their decompositions to transPtHX( 2 )] were studied. Some binuclear hydrido-bridged complexes, e.g.( 2 )HPt(μ-H)PtH( 2 )]+, were also obtained. The preparation of complexes trans-PtHX( 28 )2] (X = H or Me, 28 = bis3-(trifluoromethyl)phenyl]benzylphosphine) is also reported. The X-ray crystal structure of trans-PtHCl 1 )] ( 1 = 2,11-bis(diphenylphosphinomethyl)benzoc]phenanthrene) was carried out. |
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