Complex of vanadium(5+) with the dioxygen radical-anion in the catalyzed disproportionation of hydrogen peroxide |
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| Authors: | A. P. Makarov A. E. Gekhman V. M. Nekipelov E. P. Talzi O. Ya. Polotnyuk K. I. Zamaraev I. I. Moiseev |
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| Affiliation: | (1) N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, Moscow;(2) Research Institute for Organic Intermediates and Dyes, Moscow;(3) Institute of Catalysis, Siberian Branch, Academy of Sciences of the USSR, Moscow |
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| Abstract: | Conclusions The intermediate formation of vanadium(5+) peroxo complexes was detected under conditions of the disproportionation of hydrogen peroxide in acetic acid catalyzed by ammonium metavanadate by51V NMR spectroscopy and the complex of vanadium(5+) ions with the dioxygen radical-anion was detected by ESR spectroscopy.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1914–1917, August, 1985. |
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