Di-μ-hydroxo complexes of palladium(II) with α-diimines |
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Authors: | Sa´nchez Gregorio Sanmarti´n Antonio Garci´a Joaqui´n Lo´pez Gregorio |
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Affiliation: | (1) Departamento de Qui′mica Inorga′nica, Universidad de Murcia, 30071 Murcia, Spain |
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Abstract: | The binuclear hydroxo α-diiminate palladium complexes [Pd2(R′N=CR-CR=NR′)2(μ-OH)2][ClO4]2 (R=H, R′= C6H4Me-o or C6H4Me-p; R=Me, R′=Ph, C6H4Me-o or C6H4Me-p) have been prepared by reacting the corresponding chloro complexes with AgClO4 in Me2CO–H2O. The hydroxo complexes react with the protic electrophiles ethanoic acid, acetylacetone and8-hydroxoquinoline to give the corresponding acetylacetonate, acetate and 8-hydroxiquinolinate complexes. This revised version was published online in June 2006 with corrections to the Cover Date. |
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