Control of grain size and morphologies of nanograined ferrites by adaptation of the synthesis route: mechanosynthesis and soft chemistry

Nanocrystalline Fe-based spinels with composition Fe_2.5Ti_0.5O₄ can be synthesized using two different routes: soft chemistry and high-energy ball milling. This paper is focussed on the fact that each type of synthesis process can lead to powders with a crystallite size of about 15 nm but with significant differences in the grain size distribution and the agglomeration state. Whereas in the case of mechanosynthesis, the ball-milled powders consist of aggregates, those obtained by soft chemistry are very well dispersed. Moreover the chosen investigated nanopowders present a blocked/superparamagnetic transition depending on the grain size. The grain size morphologies obtained by the two techniques of synthesis can then be fully characterized by complementary experiments: in addition to high-resolution image processing, specific measurements adapted to the study of magnetic relaxation can be used for weighting differently their small and large size tails: namely, magnetization measurements and Mössbauer spectrometry.