Calculations of Freezing Point Depression,Boiling Point Elevation,Vapor Pressure and Enthalpies of Vaporization of Electrolyte Solutions by a Modified Three-Characteristic Parameter Correlation Model |
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Authors: | Xinlei Ge Xidong Wang |
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Institution: | (1) Department of Materials Science and Engineering, Royal Institute of Technology, 10044 Stockholm, Sweden;(2) College of Engineering, Peking University, Beijing, 100871, China |
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Abstract: | A method was proposed for calculating the thermodynamic properties, freezing point depression, boiling point elevation, vapor
pressure and enthalpy of vaporization for single solute electrolyte solutions, including aqueous and nonaqueous solutions,
based on a modified three-characteristic-parameter correlation model. When compared with the corresponding literature values,
the calculated results show that this method gives a very good approximation, especially for 1-1 electrolytes. Although the
method is not very suitable for some solutions with very high ionic strength, it is still a very useful technique when experimental
data is scarce. |
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Keywords: | Electrolyte solutions Freezing point Boiling point Enthalpy of vaporization |
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